It has been found that the mixed trimeric double Schiff bases react with transitional metal ions such as Cu(ⅱ), Ni(ⅱ), VO(ⅱ) to form the inline complexes after the C-N single bond breaks in the part of ligands. 本文发现混合三聚双席夫碱与过渡金属离子Cu(Ⅱ)、Ni(Ⅱ)、VO(Ⅱ)作用时,配体发生碳氮单键断裂后形成亚胺配合物。